1 00:00:07,760 --> 00:00:04,610 good morning or afternoon everyone 2 00:00:10,310 --> 00:00:07,770 welcome to the nai director seminar this 3 00:00:12,259 --> 00:00:10,320 is going to be the last director seminar 4 00:00:14,629 --> 00:00:12,269 before the summer break and we'll pick 5 00:00:17,900 --> 00:00:14,639 it up again at the end of September we 6 00:00:21,140 --> 00:00:17,910 are really privileged today to have 7 00:00:24,189 --> 00:00:21,150 David Blake of the nai aims team with us 8 00:00:26,720 --> 00:00:24,199 Dave as I'm sure most of the people 9 00:00:28,970 --> 00:00:26,730 listening to this and watching this know 10 00:00:30,439 --> 00:00:28,980 is the principal investigator on the 11 00:00:32,590 --> 00:00:30,449 chemin instrument which is going to fly 12 00:00:34,580 --> 00:00:32,600 to Mars on the Mars Science Laboratory 13 00:00:37,310 --> 00:00:34,590 and I was just looking at Dave's 14 00:00:39,290 --> 00:00:37,320 background and I think he has probably 15 00:00:42,170 --> 00:00:39,300 been a principal investigator and just 16 00:00:46,340 --> 00:00:42,180 about every RNA program addressing 17 00:00:49,190 --> 00:00:46,350 planetary science and astrobiology that 18 00:00:51,290 --> 00:00:49,200 nASA has ever had he's been a p.i in the 19 00:00:54,260 --> 00:00:51,300 exobiology program cosmochemistry 20 00:00:56,240 --> 00:00:54,270 ancient Mars meteorite program ace did 21 00:00:58,520 --> 00:00:56,250 Mars instrument development program 22 00:01:02,060 --> 00:00:58,530 upper atmosphere research program list 23 00:01:05,690 --> 00:01:02,070 just goes on and on so dave has had 24 00:01:08,690 --> 00:01:05,700 quite a successful career here at NASA 25 00:01:12,100 --> 00:01:08,700 he has in fact been here at NASA NASA 26 00:01:15,620 --> 00:01:12,110 Ames since he became an NRC fellow in 27 00:01:18,170 --> 00:01:15,630 1986 and has had a very distinguished 28 00:01:21,410 --> 00:01:18,180 career including presently being chief 29 00:01:24,830 --> 00:01:21,420 of the exobiology branch here at the 30 00:01:27,830 --> 00:01:24,840 center he has a bachelor's in biological 31 00:01:31,640 --> 00:01:27,840 sciences from Stanford and a master's in 32 00:01:34,069 --> 00:01:31,650 geological sciences from Michigan and a 33 00:01:36,190 --> 00:01:34,079 PhD in mineralogy from Michigan so Dave 34 00:01:37,880 --> 00:01:36,200 again represents the kind of 35 00:01:40,609 --> 00:01:37,890 interdisciplinarity within a single 36 00:01:43,880 --> 00:01:40,619 individual that we think we've invented 37 00:01:45,950 --> 00:01:43,890 here at nai but obviously it was 38 00:01:48,499 --> 00:01:45,960 invented long before us I people like 39 00:01:51,440 --> 00:01:48,509 Dave so without further ado I'll turn it 40 00:01:53,660 --> 00:01:51,450 over today bike thank actually i think 41 00:01:56,270 --> 00:01:53,670 it was invented here because my advisor 42 00:01:57,920 --> 00:01:56,280 when i graduated he the best thing he 43 00:02:02,270 --> 00:01:57,930 could say about me with that i was 44 00:02:03,940 --> 00:02:02,280 neither fish nor fowl whatever that 45 00:02:07,910 --> 00:02:03,950 means hopefully hopefully something good 46 00:02:10,699 --> 00:02:07,920 well I i wanted to talk a bit today 47 00:02:11,450 --> 00:02:10,709 about the chemin instrument and msl and 48 00:02:15,980 --> 00:02:11,460 one 49 00:02:17,750 --> 00:02:15,990 know that NASA wants all of us 50 00:02:21,980 --> 00:02:17,760 scientists to getting more involved with 51 00:02:24,620 --> 00:02:21,990 missions and I know the nii here at Ames 52 00:02:27,020 --> 00:02:24,630 is trying to do that by getting involved 53 00:02:30,140 --> 00:02:27,030 with Kevin and with ms l and I wanted 54 00:02:33,350 --> 00:02:30,150 all for that opportunity to do anyone 55 00:02:37,280 --> 00:02:33,360 who wanted to do that so let me begin by 56 00:02:39,110 --> 00:02:37,290 speaking a bit about about msl and what 57 00:02:41,270 --> 00:02:39,120 it is is going to mostly be boilerplate 58 00:02:43,280 --> 00:02:41,280 because I hope that you you know about 59 00:02:45,770 --> 00:02:43,290 that already and then I'll get into the 60 00:02:49,060 --> 00:02:45,780 chemin instrument and how this might be 61 00:02:56,320 --> 00:02:49,070 useful for what you folks are doing so 62 00:02:59,420 --> 00:02:56,330 okay let's start off well a NASA 63 00:03:02,140 --> 00:02:59,430 exploration program this is this is also 64 00:03:04,370 --> 00:03:02,150 pretty much boilerplate presently 65 00:03:07,790 --> 00:03:04,380 Phoenix is on the ground in getting some 66 00:03:09,380 --> 00:03:07,800 pretty good data and october two 67 00:03:12,250 --> 00:03:09,390 thousand nine is the launch of Mars 68 00:03:15,740 --> 00:03:12,260 Science Laboratory and it'll land in 69 00:03:17,450 --> 00:03:15,750 mid-2010 and be active on the surface 70 00:03:19,970 --> 00:03:17,460 hopefully for at least two years and 71 00:03:23,750 --> 00:03:19,980 then what happens after that no one 72 00:03:26,240 --> 00:03:23,760 knows depending upon what discoveries we 73 00:03:30,500 --> 00:03:26,250 make and and what NASA policy is at that 74 00:03:33,680 --> 00:03:30,510 time well msl and chemin science goals 75 00:03:35,870 --> 00:03:33,690 the MSL science objective is to explore 76 00:03:37,460 --> 00:03:35,880 and quantitatively assess a local region 77 00:03:41,050 --> 00:03:37,470 on the Mars surface as a potential 78 00:03:43,780 --> 00:03:41,060 habitat for past or present life and 79 00:03:47,390 --> 00:03:43,790 there are four main science objectives 80 00:03:49,700 --> 00:03:47,400 assess the biological potential of a one 81 00:03:52,100 --> 00:03:49,710 target environment characterized the 82 00:03:54,920 --> 00:03:52,110 geology and geochemistry of the landed 83 00:03:56,800 --> 00:03:54,930 region investigate processes of 84 00:04:00,830 --> 00:03:56,810 relevance to past habitability and 85 00:04:02,570 --> 00:04:00,840 characterize surface radiation chemin is 86 00:04:04,940 --> 00:04:02,580 going to be involved in three of those 87 00:04:06,680 --> 00:04:04,950 goals to starred ones here assess the 88 00:04:10,550 --> 00:04:06,690 biological potential characterize 89 00:04:15,890 --> 00:04:10,560 geology investigate processes relevant 90 00:04:18,110 --> 00:04:15,900 to past habitability so just to show you 91 00:04:20,510 --> 00:04:18,120 what MSL looks like in comparison to mur 92 00:04:23,480 --> 00:04:20,520 it's a lot bigger this is ms l in the 93 00:04:25,250 --> 00:04:23,490 front and the main difference aside from 94 00:04:27,530 --> 00:04:25,260 size you can see is 95 00:04:30,770 --> 00:04:27,540 msl is operated with a radio thermal 96 00:04:34,960 --> 00:04:30,780 generator so its nuclear powered MSL is 97 00:04:37,400 --> 00:04:34,970 run or rather amigas or run by solar 98 00:04:39,170 --> 00:04:37,410 there's a size comparison i don't know 99 00:04:41,780 --> 00:04:39,180 if anybody really understands just how 100 00:04:44,270 --> 00:04:41,790 big this thing is but it just about 101 00:04:46,280 --> 00:04:44,280 dwarfs of mini cooper and i've never 102 00:04:49,160 --> 00:04:46,290 seen this close up but i've seen some of 103 00:04:52,700 --> 00:04:49,170 the onesies for testing the landing and 104 00:04:54,440 --> 00:04:52,710 the top of the surface just about his 105 00:04:56,930 --> 00:04:54,450 chest high on me and these wheels are 106 00:05:01,820 --> 00:04:56,940 about half a half a meter in diameter so 107 00:05:03,680 --> 00:05:01,830 it's it's big they started out there 108 00:05:06,920 --> 00:05:03,690 were coming up on our third landing site 109 00:05:10,180 --> 00:05:06,930 workshop the first landing site workshop 110 00:05:12,620 --> 00:05:10,190 there were something like 30 or 40 111 00:05:15,500 --> 00:05:12,630 individual sites proposed and these were 112 00:05:17,920 --> 00:05:15,510 investigated by high rise and some of 113 00:05:20,690 --> 00:05:17,930 the other orbital assets on Mars and 114 00:05:24,050 --> 00:05:20,700 they've been window down to six with the 115 00:05:25,610 --> 00:05:24,060 potential seven and you can look on the 116 00:05:28,730 --> 00:05:25,620 web and see what's interesting about 117 00:05:31,640 --> 00:05:28,740 each of these sites but they all have to 118 00:05:35,420 --> 00:05:31,650 do with either with water with with 119 00:05:39,710 --> 00:05:35,430 either phyllosilicates or with the 120 00:05:41,390 --> 00:05:39,720 sulfates here's the MSL payload there's 121 00:05:44,060 --> 00:05:41,400 there's four elements to it there's a 122 00:05:47,540 --> 00:05:44,070 remote sensing element which has a mask 123 00:05:50,600 --> 00:05:47,550 am similar to what the mers have a chem 124 00:05:52,520 --> 00:05:50,610 cam which is a Laser ionization tool 125 00:05:56,690 --> 00:05:52,530 where you can actually see compositions 126 00:05:59,090 --> 00:05:56,700 at a distance then there are contacts 127 00:06:01,190 --> 00:05:59,100 instruments including the Molly Kenna 128 00:06:04,420 --> 00:06:01,200 Jets instrument which is for microscopic 129 00:06:08,720 --> 00:06:04,430 imaging it's like a geologist hand lens 130 00:06:10,640 --> 00:06:08,730 the apxs which is flown on the Merse and 131 00:06:13,250 --> 00:06:10,650 it will tell you elemental composition 132 00:06:15,620 --> 00:06:13,260 and then inside the body of the rover 133 00:06:18,820 --> 00:06:15,630 there are two analytical instruments the 134 00:06:22,340 --> 00:06:18,830 Sam instrument which is a GC mass spec 135 00:06:24,170 --> 00:06:22,350 from Paul Mahaffy at Goddard that's kind 136 00:06:28,010 --> 00:06:24,180 of like the 500-pound gorilla on the 137 00:06:32,480 --> 00:06:28,020 payload then Kevin is also inside there 138 00:06:35,300 --> 00:06:32,490 and it's about a 10 kilogram xrd XRF 139 00:06:37,210 --> 00:06:35,310 instrument and then right around the 140 00:06:39,660 --> 00:06:37,220 around the outside of the land 141 00:06:41,920 --> 00:06:39,670 or the rover there's the Marty 142 00:06:44,620 --> 00:06:41,930 instrument which is strictly for descent 143 00:06:48,220 --> 00:06:44,630 imagery there's the Rams instrument 144 00:06:49,840 --> 00:06:48,230 which is a meteorology tool for 145 00:06:53,410 --> 00:06:49,850 determining wind speed and so forth 146 00:06:55,150 --> 00:06:53,420 there's the rad instrument which tells 147 00:06:57,640 --> 00:06:55,160 you about radiation on the surface and 148 00:07:00,700 --> 00:06:57,650 then there's the Dan instrument which is 149 00:07:04,300 --> 00:07:00,710 a neutron generator and detector to 150 00:07:10,360 --> 00:07:04,310 determine subsurface hydrogen and I was 151 00:07:12,130 --> 00:07:10,370 talking to Dmitry metropolis and the 152 00:07:13,300 --> 00:07:12,140 interesting thing about the Dan is that 153 00:07:15,700 --> 00:07:13,310 this really is swords to plowshares 154 00:07:17,620 --> 00:07:15,710 because the neutron generator and that 155 00:07:19,090 --> 00:07:17,630 thing is a nuclear trigger from a 156 00:07:21,550 --> 00:07:19,100 Russian atomic bomb so I thought that 157 00:07:22,990 --> 00:07:21,560 was I was pretty interesting I'd like to 158 00:07:26,080 --> 00:07:23,000 see the u.s. pull that kind of a thing 159 00:07:30,250 --> 00:07:26,090 off on a Russian mission okay let's get 160 00:07:33,250 --> 00:07:30,260 to chemin well the I'm the pie and it's 161 00:07:36,610 --> 00:07:33,260 being built by JPL but it's it's coming 162 00:07:39,100 --> 00:07:36,620 out of an answer research center there 163 00:07:42,430 --> 00:07:39,110 is a microphone okis x-ray tube that 164 00:07:44,740 --> 00:07:42,440 produces a small beam about 50 microns 165 00:07:47,980 --> 00:07:44,750 in diameter that goes through pennell 166 00:07:49,690 --> 00:07:47,990 collimator to illuminate the the sample 167 00:07:51,400 --> 00:07:49,700 sale here which consists of two thin 168 00:07:54,550 --> 00:07:51,410 plastic windows with fine grain material 169 00:07:58,110 --> 00:07:54,560 in between and then the photons are 170 00:08:01,570 --> 00:07:58,120 detected by this x-ray sensitive ccd and 171 00:08:03,670 --> 00:08:01,580 i'll talk more about this later but just 172 00:08:07,330 --> 00:08:03,680 to say now that chemin is able to do 173 00:08:08,650 --> 00:08:07,340 definitive mineralogy and be able to 174 00:08:11,350 --> 00:08:08,660 determine all possible all the minerals 175 00:08:12,850 --> 00:08:11,360 that are on Mars and if we don't know if 176 00:08:14,380 --> 00:08:12,860 we find a mineral that we didn't see 177 00:08:18,700 --> 00:08:14,390 before we'll be able to name it and tell 178 00:08:21,940 --> 00:08:18,710 you what it is here's the most recent 179 00:08:24,040 --> 00:08:21,950 picture of the rover the main things 180 00:08:28,870 --> 00:08:24,050 that have changed our things around the 181 00:08:31,900 --> 00:08:28,880 SAS bow on the arm here nothing to much 182 00:08:33,760 --> 00:08:31,910 of interest chemin is sitting inside the 183 00:08:36,040 --> 00:08:33,770 rover and there's a little access port 184 00:08:37,959 --> 00:08:36,050 right about here when they generate 185 00:08:40,180 --> 00:08:37,969 material for us they open a little 186 00:08:44,110 --> 00:08:40,190 access port dump in the material and 187 00:08:47,860 --> 00:08:44,120 then we analyze it so here's the summary 188 00:08:49,960 --> 00:08:47,870 of spreadsheet of Investigations versus 189 00:08:50,950 --> 00:08:49,970 objectives these are all the objectives 190 00:08:52,990 --> 00:08:50,960 on this 191 00:08:55,990 --> 00:08:53,000 of what MSL was supposed to do and 192 00:08:58,750 --> 00:08:56,000 here's the the various ways that the 193 00:08:59,890 --> 00:08:58,760 instruments support those objectives so 194 00:09:01,750 --> 00:08:59,900 you can see there's a lot of redundancy 195 00:09:05,920 --> 00:09:01,760 in the package and that's kind of like 196 00:09:07,750 --> 00:09:05,930 what they were going for so not like to 197 00:09:11,370 --> 00:09:07,760 go into the mineralogy aspect to this 198 00:09:13,930 --> 00:09:11,380 why do we care about mineralogy on Mars 199 00:09:15,940 --> 00:09:13,940 mineralogy is it really the only means 200 00:09:18,910 --> 00:09:15,950 to lucid eight environments in the 201 00:09:20,830 --> 00:09:18,920 geologically ancient past minerals are 202 00:09:23,530 --> 00:09:20,840 thermodynamic phases and by that I mean 203 00:09:24,910 --> 00:09:23,540 that they form under certain conditions 204 00:09:28,690 --> 00:09:24,920 of temperature pressure and Composition 205 00:09:30,760 --> 00:09:28,700 and by seeing a mineral with it you can 206 00:09:33,700 --> 00:09:30,770 tell what pressure temperature and 207 00:09:37,240 --> 00:09:33,710 Composition surrounded it when it was 208 00:09:38,770 --> 00:09:37,250 formed the second thing that's that 209 00:09:41,890 --> 00:09:38,780 helps us is that solid state 210 00:09:44,590 --> 00:09:41,900 transformations are sluggish so minerals 211 00:09:46,810 --> 00:09:44,600 quite often stay in an unrequited state 212 00:09:49,030 --> 00:09:46,820 after their forms so we can see them and 213 00:09:50,620 --> 00:09:49,040 know what condition they were formed and 214 00:09:52,750 --> 00:09:50,630 even even though they're present now in 215 00:09:54,190 --> 00:09:52,760 a different condition so if you happen 216 00:09:55,990 --> 00:09:54,200 to find a diamond on the ground which 217 00:09:57,670 --> 00:09:56,000 would be a good thing you could say that 218 00:09:59,110 --> 00:09:57,680 that diamond was not formed in that 219 00:10:03,390 --> 00:09:59,120 environment it was informed in a 220 00:10:05,860 --> 00:10:03,400 high-pressure environment somewhere else 221 00:10:08,410 --> 00:10:05,870 secondly our thirdly rather relic 222 00:10:11,530 --> 00:10:08,420 biological information might be cryptic 223 00:10:14,910 --> 00:10:11,540 and so you need to have mineralogy to 224 00:10:17,940 --> 00:10:14,920 find the rocks that may have a relic by 225 00:10:20,530 --> 00:10:17,950 bio information inside of them so 226 00:10:23,590 --> 00:10:20,540 mineralogy is a good tool to find what 227 00:10:26,020 --> 00:10:23,600 rocks might contain bio signatures 228 00:10:27,730 --> 00:10:26,030 within them and then lastly weathering 229 00:10:29,830 --> 00:10:27,740 and diagenesis might only leave the 230 00:10:33,610 --> 00:10:29,840 mineral component of a biological 231 00:10:34,960 --> 00:10:33,620 process the the phrase I like to say is 232 00:10:37,060 --> 00:10:34,970 that anything older than a few million 233 00:10:39,490 --> 00:10:37,070 years on Mars is either going to be Iraq 234 00:10:40,750 --> 00:10:39,500 or it's only going to be interpreted 235 00:10:45,610 --> 00:10:40,760 well in terms of the rocks that contain 236 00:10:49,030 --> 00:10:45,620 it so let's talk about mineralogy in the 237 00:10:52,690 --> 00:10:49,040 context of some rocks that were seen by 238 00:10:56,350 --> 00:10:52,700 the rover's here you see a table of a 239 00:10:58,090 --> 00:10:56,360 bunch of rocks from Gusev crater these 240 00:11:01,030 --> 00:10:58,100 are watched what called watched our 241 00:11:03,700 --> 00:11:01,040 class rocks there's Keystone keel davis 242 00:11:06,940 --> 00:11:03,710 Watchtower Pequod and pero 243 00:11:09,550 --> 00:11:06,950 and you can see from the apx data here 244 00:11:12,910 --> 00:11:09,560 they're all pretty much the same 245 00:11:14,200 --> 00:11:12,920 chemically so if you do a px of all of 246 00:11:17,230 --> 00:11:14,210 these rocks they all pretty much look 247 00:11:19,330 --> 00:11:17,240 the same but over here you see mas power 248 00:11:21,460 --> 00:11:19,340 results and each one of these colors 249 00:11:24,010 --> 00:11:21,470 represents a different iron mineral and 250 00:11:27,040 --> 00:11:24,020 you can see that the mineralogy of these 251 00:11:29,500 --> 00:11:27,050 rocks at least when looked at from a 252 00:11:31,900 --> 00:11:29,510 mineralogical perspective they from from 253 00:11:34,810 --> 00:11:31,910 the iron minerals rather are very 254 00:11:38,500 --> 00:11:34,820 diverse so mineralogy will tell you the 255 00:11:40,930 --> 00:11:38,510 dye vs. but the diverse environments of 256 00:11:45,550 --> 00:11:40,940 a surface whereas chemical composition 257 00:11:47,380 --> 00:11:45,560 alone might not so here's the chemin 258 00:11:50,530 --> 00:11:47,390 principle chemin stands for chemistry 259 00:11:53,830 --> 00:11:50,540 and mineralogy it uses x-ray diffraction 260 00:11:55,420 --> 00:11:53,840 for mineralogical determinations x-ray 261 00:11:58,060 --> 00:11:55,430 fluorescence for elemental 262 00:12:01,570 --> 00:11:58,070 characterization a single detector for 263 00:12:03,910 --> 00:12:01,580 both measurements and no moving parts in 264 00:12:05,590 --> 00:12:03,920 about 20 milligrams sample size so it's 265 00:12:09,040 --> 00:12:05,600 a little bit smaller than a baby aspirin 266 00:12:11,800 --> 00:12:09,050 tablet size of sample so now I'll give 267 00:12:15,580 --> 00:12:11,810 you a little brief insight into how it 268 00:12:18,130 --> 00:12:15,590 works cobalt x-ray tube microfocus tube 269 00:12:20,620 --> 00:12:18,140 it a beam starts here at about 50 270 00:12:22,780 --> 00:12:20,630 microns diameter there is a pinhole 271 00:12:25,870 --> 00:12:22,790 kilometer which produces a collimated 272 00:12:29,350 --> 00:12:25,880 proximately 50 micron source it goes 273 00:12:31,150 --> 00:12:29,360 through a thin too thin plastic films 274 00:12:33,790 --> 00:12:31,160 which contain the sample between them 275 00:12:37,150 --> 00:12:33,800 the sample consists of 150 microns and 276 00:12:40,180 --> 00:12:37,160 below crush powders and this whole thing 277 00:12:42,580 --> 00:12:40,190 is shaken so that the the powder flows 278 00:12:45,160 --> 00:12:42,590 like liquid inside this cell so that in 279 00:12:47,950 --> 00:12:45,170 over a period of time all the grains 280 00:12:50,050 --> 00:12:47,960 fast through this tiny beam in random 281 00:12:52,840 --> 00:12:50,060 orientations and as they pass through 282 00:12:55,510 --> 00:12:52,850 the beam two possible things can happen 283 00:12:57,850 --> 00:12:55,520 nothing can happen of course but one 284 00:12:59,890 --> 00:12:57,860 possible thing is diffraction and the 285 00:13:04,120 --> 00:12:59,900 diffracted beam the form these lousy 286 00:13:06,040 --> 00:13:04,130 rings on the ccd detector here the 287 00:13:09,520 --> 00:13:06,050 second thing that can happen is that you 288 00:13:11,410 --> 00:13:09,530 can get x-ray fluorescence and photons 289 00:13:13,480 --> 00:13:11,420 are emitted from the sample which have 290 00:13:16,120 --> 00:13:13,490 energies which tell you what element 291 00:13:17,290 --> 00:13:16,130 elements are in the sample and so this 292 00:13:20,139 --> 00:13:17,300 detector can 293 00:13:23,410 --> 00:13:20,149 both of those signals at once if you if 294 00:13:26,110 --> 00:13:23,420 you do a dative plot which is basically 295 00:13:28,480 --> 00:13:26,120 from the center outwards of these 296 00:13:30,970 --> 00:13:28,490 photons that are striking the Rings then 297 00:13:34,230 --> 00:13:30,980 you will get this this thing here this 298 00:13:37,750 --> 00:13:34,240 one dimensional plot diffractograms and 299 00:13:39,130 --> 00:13:37,760 this will tell you what spacings are 300 00:13:41,769 --> 00:13:39,140 present in all the minerals that are 301 00:13:43,509 --> 00:13:41,779 contained in the sample if you just take 302 00:13:45,340 --> 00:13:43,519 all the energies of the photons and 303 00:13:47,620 --> 00:13:45,350 strike the chip and make a histogram 304 00:13:49,269 --> 00:13:47,630 down here this will tell you all the 305 00:13:51,130 --> 00:13:49,279 elements at our present so with these 306 00:13:53,079 --> 00:13:51,140 two measurements you can tell the 307 00:13:55,540 --> 00:13:53,089 composition and scent of the sample from 308 00:13:56,829 --> 00:13:55,550 the x-ray fluorescence and the structure 309 00:14:01,300 --> 00:13:56,839 of the sample from the diffraction 310 00:14:03,430 --> 00:14:01,310 information so now that we know that 311 00:14:05,230 --> 00:14:03,440 what what we know the geometry it's a 312 00:14:07,509 --> 00:14:05,240 transmission geometry now we have to 313 00:14:09,579 --> 00:14:07,519 worry about the details of where do we 314 00:14:12,340 --> 00:14:09,589 want to look what what to theta angles 315 00:14:14,259 --> 00:14:12,350 what range what resolution we know that 316 00:14:16,780 --> 00:14:14,269 we would like to see in the low to theta 317 00:14:18,100 --> 00:14:16,790 regions because we want to see clays and 318 00:14:21,220 --> 00:14:18,110 that's where the principal peaks of 319 00:14:23,590 --> 00:14:21,230 clays are located here's xrd pattern of 320 00:14:25,210 --> 00:14:23,600 smectite and you can see this is the 321 00:14:27,730 --> 00:14:25,220 principle peak of smectite and that's 322 00:14:30,340 --> 00:14:27,740 located down around five or six degrees 323 00:14:32,980 --> 00:14:30,350 two theta so we want to have an angular 324 00:14:34,720 --> 00:14:32,990 range that will encompass place we also 325 00:14:39,639 --> 00:14:34,730 want to go out far enough to encompass 326 00:14:41,560 --> 00:14:39,649 other other minerals of interest so we 327 00:14:43,300 --> 00:14:41,570 this is a little bit of Monday morning 328 00:14:44,860 --> 00:14:43,310 quarterbacking we actually knew where we 329 00:14:46,630 --> 00:14:44,870 wanted to go with this instrument but 330 00:14:50,530 --> 00:14:46,640 when we went through the science peer 331 00:14:53,319 --> 00:14:50,540 review down at JPL to justify our to 332 00:14:55,449 --> 00:14:53,329 theta range we took a mineral model of 333 00:14:58,540 --> 00:14:55,459 the piece outcrop and the Columbia Hills 334 00:15:00,400 --> 00:14:58,550 done by Doug Ming this shows you each 335 00:15:02,650 --> 00:15:00,410 one of the minerals that were present in 336 00:15:05,519 --> 00:15:02,660 that model forsterite which is an 337 00:15:07,650 --> 00:15:05,529 olivene augite which is a Pyrrhic seen 338 00:15:11,530 --> 00:15:07,660 labradorite which is a feldspar 339 00:15:13,660 --> 00:15:11,540 magnetite claire appetite Kizer right 340 00:15:16,300 --> 00:15:13,670 gypsum and this is all of them together 341 00:15:19,480 --> 00:15:16,310 this shows the major peaks all these 342 00:15:21,340 --> 00:15:19,490 small lines for each mineral you can see 343 00:15:22,990 --> 00:15:21,350 there are very complex ones like the 344 00:15:25,660 --> 00:15:23,000 labradorite which has a lot of lines 345 00:15:28,389 --> 00:15:25,670 together simple ones like magnetite 346 00:15:31,150 --> 00:15:28,399 which is a cubic feet or rather cubic 347 00:15:33,670 --> 00:15:31,160 phase when you put them all together you 348 00:15:35,470 --> 00:15:33,680 kind of a mishmash here and the main 349 00:15:38,050 --> 00:15:35,480 point we wanted to make with this is 350 00:15:41,650 --> 00:15:38,060 that if you look at the two theta range 351 00:15:43,329 --> 00:15:41,660 from about 5 out to about 50 you can get 352 00:15:46,540 --> 00:15:43,339 all the major peaks of interest for 353 00:15:49,059 --> 00:15:46,550 these phases okay so let's go on to look 354 00:15:51,730 --> 00:15:49,069 at what kind of we know we know the 355 00:15:54,639 --> 00:15:51,740 range of 2 theta we want what kind of 356 00:15:56,050 --> 00:15:54,649 resolution do we want and we can't just 357 00:15:58,210 --> 00:15:56,060 have the best resolution possible 358 00:16:01,090 --> 00:15:58,220 because resolution is inversely 359 00:16:03,730 --> 00:16:01,100 proportional to count rate so we want to 360 00:16:06,759 --> 00:16:03,740 have the basically the worst resolution 361 00:16:10,420 --> 00:16:06,769 that will give us the answer that we can 362 00:16:14,050 --> 00:16:10,430 live with so what we did is we we made a 363 00:16:17,350 --> 00:16:14,060 model of these minerals and use various 364 00:16:19,660 --> 00:16:17,360 resolutions here from point 3 I know you 365 00:16:22,210 --> 00:16:19,670 can't see the colors here all together 366 00:16:24,699 --> 00:16:22,220 with 0 point 3 to about point six 367 00:16:27,730 --> 00:16:24,709 degrees two theta and if we go to the 368 00:16:30,579 --> 00:16:27,740 next slide here we'll just look at a 369 00:16:33,220 --> 00:16:30,589 small range from 30 to 32 degrees two 370 00:16:35,069 --> 00:16:33,230 theta you can see that as we go from 371 00:16:38,410 --> 00:16:35,079 about point three degrees two theta 372 00:16:40,600 --> 00:16:38,420 downward we start to lose the ability to 373 00:16:44,499 --> 00:16:40,610 distinguish these peaks and therefore to 374 00:16:46,150 --> 00:16:44,509 distinguish these minerals so we were as 375 00:16:49,150 --> 00:16:46,160 we would like to have the very best 376 00:16:51,790 --> 00:16:49,160 possible resolution on this instrument 377 00:16:53,889 --> 00:16:51,800 we can put up with between about point 378 00:16:56,350 --> 00:16:53,899 three and point three five and actually 379 00:17:00,280 --> 00:16:56,360 do the job and just for comparison a 380 00:17:03,040 --> 00:17:00,290 laboratory diffractometer that you might 381 00:17:05,409 --> 00:17:03,050 buy has a full with half max of about 382 00:17:07,510 --> 00:17:05,419 point one so we're about three times 383 00:17:09,850 --> 00:17:07,520 worse than a laboratory diffractometer 384 00:17:13,179 --> 00:17:09,860 but nevertheless we're able to do what 385 00:17:17,230 --> 00:17:13,189 we say we can do and here's an example 386 00:17:21,340 --> 00:17:17,240 of a data set from from a typical chemin 387 00:17:24,100 --> 00:17:21,350 run here's the 2d energy filtered xrd 388 00:17:27,039 --> 00:17:24,110 pattern and here is the diffractograms 389 00:17:29,620 --> 00:17:27,049 that was obtained from that pattern this 390 00:17:31,690 --> 00:17:29,630 is what's called a repelled refinement 391 00:17:34,510 --> 00:17:31,700 which is a both pattern fitting with 392 00:17:37,210 --> 00:17:34,520 lise where's refinement and by doing 393 00:17:40,539 --> 00:17:37,220 this kind of a quantitative analysis you 394 00:17:42,880 --> 00:17:40,549 can get a fully quantitative analysis of 395 00:17:46,300 --> 00:17:42,890 all the minerals that are present there 396 00:17:48,010 --> 00:17:46,310 this was done by Dave fish at Indiana 397 00:17:50,560 --> 00:17:48,020 University who's one of the people on 398 00:17:53,140 --> 00:17:50,570 our team you can also get friending more 399 00:17:54,820 --> 00:17:53,150 than about ten percent president about 400 00:17:57,460 --> 00:17:54,830 ten percent composition you can get 401 00:17:59,170 --> 00:17:57,470 refined lattice parameters and with 402 00:18:01,450 --> 00:17:59,180 refined lattice parameters with things 403 00:18:03,880 --> 00:18:01,460 like olive eens you can tell the iron 404 00:18:06,460 --> 00:18:03,890 magnesium ratio and so forth and then 405 00:18:08,500 --> 00:18:06,470 here's the x-ray fluorescence pattern 406 00:18:10,840 --> 00:18:08,510 from this sample this particular camera 407 00:18:12,520 --> 00:18:10,850 have a bit of iron contamination we want 408 00:18:15,220 --> 00:18:12,530 to really have that issue on a myself 409 00:18:20,320 --> 00:18:15,230 but that's what a standard data set will 410 00:18:23,470 --> 00:18:20,330 look like now now that we know what full 411 00:18:25,600 --> 00:18:23,480 range and all that is necessary what 412 00:18:28,780 --> 00:18:25,610 kind of accuracy and precision do we 413 00:18:32,230 --> 00:18:28,790 want this shows the accuracy of the 414 00:18:34,780 --> 00:18:32,240 chemcam instrument and the apxs and the 415 00:18:36,310 --> 00:18:34,790 precision and we picked an accuracy of 416 00:18:38,590 --> 00:18:36,320 about fifteen percent of the amount 417 00:18:41,110 --> 00:18:38,600 present we can actually do better than 418 00:18:42,580 --> 00:18:41,120 that but this is our requirement this is 419 00:18:47,620 --> 00:18:42,590 what we have to show in order to be 420 00:18:51,010 --> 00:18:47,630 fully responsive to to to our contract 421 00:18:52,960 --> 00:18:51,020 and a ten percent precision with a 422 00:18:54,790 --> 00:18:52,970 minimum detection level of about three 423 00:18:56,500 --> 00:18:54,800 percent and we can actually do better 424 00:19:02,260 --> 00:18:56,510 than this but this is what we signed up 425 00:19:04,420 --> 00:19:02,270 for here's a couple of examples this is 426 00:19:08,170 --> 00:19:04,430 a Hawaiian soil collected collected by 427 00:19:10,840 --> 00:19:08,180 Dick Morris it shows the minerals 428 00:19:13,360 --> 00:19:10,850 present down here this shows what are 429 00:19:15,640 --> 00:19:13,370 our trial horse chemin pour instrument 430 00:19:18,700 --> 00:19:15,650 was able to obtain this is a standard 431 00:19:20,290 --> 00:19:18,710 x-ray diffractometer analysis this is 432 00:19:22,750 --> 00:19:20,300 the percentage difference between the 433 00:19:26,080 --> 00:19:22,760 two and this is our evaluation so 434 00:19:29,860 --> 00:19:26,090 basically all of the phases that are 435 00:19:33,340 --> 00:19:29,870 above three percent are within fifteen 436 00:19:35,620 --> 00:19:33,350 percent this same orfice face here we 437 00:19:37,450 --> 00:19:35,630 had a little difficulty with and we knew 438 00:19:39,580 --> 00:19:37,460 all along we have difficulty with 439 00:19:42,190 --> 00:19:39,590 amorphous materials and we're developing 440 00:19:44,950 --> 00:19:42,200 models for that the rough these are 441 00:19:47,200 --> 00:19:44,960 below the minimum detection limits with 442 00:19:49,450 --> 00:19:47,210 with exception of kaolin iden and clays 443 00:19:51,010 --> 00:19:49,460 were we can't quite do what we say we 444 00:19:55,750 --> 00:19:51,020 can do we're more like ten percent with 445 00:19:57,340 --> 00:19:55,760 plays here's another example is a 446 00:19:59,770 --> 00:19:57,350 synthetic clay bettering 447 00:20:03,700 --> 00:19:59,780 right and here again there's none 448 00:20:06,130 --> 00:20:03,710 tonight gypsum halite hematite that's 449 00:20:08,470 --> 00:20:06,140 what Kevin for data produced that's the 450 00:20:10,930 --> 00:20:08,480 known mixture and this is the deviation 451 00:20:13,029 --> 00:20:10,940 in percent and these are all within our 452 00:20:19,029 --> 00:20:13,039 stated precision and accuracy of 453 00:20:20,560 --> 00:20:19,039 analysis okay so I was interested to see 454 00:20:23,140 --> 00:20:20,570 what we could do with some amorphous 455 00:20:24,789 --> 00:20:23,150 materials so I got together I don't 456 00:20:26,680 --> 00:20:24,799 really think you can probably see the 457 00:20:28,539 --> 00:20:26,690 labels very well but I got together as 458 00:20:32,039 --> 00:20:28,549 many Amorphis silica materials as I 459 00:20:34,600 --> 00:20:32,049 could this was to kind of look at 460 00:20:37,360 --> 00:20:34,610 similar materials to thee to the 461 00:20:41,080 --> 00:20:37,370 amorphous silica that they saw at home 462 00:20:45,789 --> 00:20:41,090 plate in maury so the lot the lines here 463 00:20:47,500 --> 00:20:45,799 you see there's opal a which is right 464 00:20:51,640 --> 00:20:47,510 there let's see I believe that so play 465 00:20:54,840 --> 00:20:51,650 right there opal CT a few silica in the 466 00:20:59,399 --> 00:20:54,850 red and guys are right in the dark blue 467 00:21:02,110 --> 00:20:59,409 down here here's a fulgurite which is a 468 00:21:05,220 --> 00:21:02,120 lightning strike amorphis ports it's 469 00:21:08,500 --> 00:21:05,230 when lightning strikes san sandstone 470 00:21:11,860 --> 00:21:08,510 then there's moldavite here moldavite is 471 00:21:14,529 --> 00:21:11,870 from Moldavia Czechoslovakia that's 472 00:21:17,020 --> 00:21:14,539 basically a tektite like material caused 473 00:21:19,529 --> 00:21:17,030 by me right impact and then here's a 474 00:21:24,340 --> 00:21:19,539 tektite that I bought at the AG you and 475 00:21:28,210 --> 00:21:24,350 then over here is a couple of ash ash 476 00:21:29,440 --> 00:21:28,220 fall tips from New Mexico so basically 477 00:21:31,659 --> 00:21:29,450 the point I want to make even without 478 00:21:33,010 --> 00:21:31,669 looking into the details is every single 479 00:21:35,230 --> 00:21:33,020 one of these is different and we can 480 00:21:37,409 --> 00:21:35,240 quantitatively analyze even amorphous 481 00:21:40,360 --> 00:21:37,419 materials and tell you what they are 482 00:21:42,940 --> 00:21:40,370 okay so let's move on a bit here here's 483 00:21:45,580 --> 00:21:42,950 a little heritage of what of what we've 484 00:21:49,390 --> 00:21:45,590 done since 1991 this was our first 485 00:21:51,760 --> 00:21:49,400 instrument built off big Phillips tube 486 00:21:53,470 --> 00:21:51,770 tower the weight of the instruments 500 487 00:21:57,700 --> 00:21:53,480 kilograms that obviously was going to go 488 00:22:00,220 --> 00:21:57,710 anywhere on 2002 we got a bit better 489 00:22:03,960 --> 00:22:00,230 x-ray tube and power supply we dropped 490 00:22:06,640 --> 00:22:03,970 wait a little bit to 100 kilograms and 491 00:22:09,130 --> 00:22:06,650 2004 when we started getting our major 492 00:22:10,150 --> 00:22:09,140 funding we were able to make a field 493 00:22:13,450 --> 00:22:10,160 instrument which 494 00:22:15,070 --> 00:22:13,460 about 30 kilograms and we actually took 495 00:22:17,650 --> 00:22:15,080 this out to death valley and did some 496 00:22:20,050 --> 00:22:17,660 tests with it from there we moved on in 497 00:22:22,930 --> 00:22:20,060 two directions this was used as a trial 498 00:22:25,030 --> 00:22:22,940 horse to build the Mars instrument which 499 00:22:27,280 --> 00:22:25,040 is over here it's actually being put 500 00:22:31,150 --> 00:22:27,290 together now and will be delivered by 501 00:22:32,500 --> 00:22:31,160 JPL in September and it's pretty pretty 502 00:22:34,420 --> 00:22:32,510 interesting to go down and clean room 503 00:22:36,640 --> 00:22:34,430 and put a little your cleanroom garb on 504 00:22:38,740 --> 00:22:36,650 and let's see what they're up to it's 505 00:22:41,740 --> 00:22:38,750 like having your own space shuttle bill 506 00:22:43,780 --> 00:22:41,750 for you it's just a lot of fun over here 507 00:22:46,030 --> 00:22:43,790 shows the second course we went with 508 00:22:48,880 --> 00:22:46,040 this Philippe Sarah's and who was my 509 00:22:50,770 --> 00:22:48,890 postdoc years ago started a little 510 00:22:53,380 --> 00:22:50,780 company called in situ in Mountain View 511 00:22:56,980 --> 00:22:53,390 and he's still working with me he's a co 512 00:22:58,690 --> 00:22:56,990 I on chemin and he's building these what 513 00:23:01,090 --> 00:22:58,700 we're now calling Tara instruments which 514 00:23:03,070 --> 00:23:01,100 are merciless a labelled and they are 515 00:23:06,100 --> 00:23:03,080 instruments with the same geometry as 516 00:23:07,510 --> 00:23:06,110 the chemin instrument but can be taken 517 00:23:11,140 --> 00:23:07,520 in the field they're filled ruggedized 518 00:23:15,430 --> 00:23:11,150 and and user-friendly so let's go on 519 00:23:17,530 --> 00:23:15,440 here's our to our trial horses this is 520 00:23:20,590 --> 00:23:17,540 our chem and for instrument which we use 521 00:23:22,480 --> 00:23:20,600 to benchmark the MSL instrument then 522 00:23:24,550 --> 00:23:22,490 this is a bit more user-friendly 523 00:23:26,650 --> 00:23:24,560 instrument are Terra instrument that's 524 00:23:30,790 --> 00:23:26,660 that we took out in the field for the 525 00:23:35,140 --> 00:23:30,800 first time in Spitsbergen last year this 526 00:23:36,550 --> 00:23:35,150 one wait about 30 kilograms and bishan 527 00:23:39,100 --> 00:23:36,560 ik daar dunnnnn off a mountain in 528 00:23:41,140 --> 00:23:39,110 Spitsbergen in 2006 and about I about 529 00:23:43,330 --> 00:23:41,150 died I knew that was not going to be the 530 00:23:45,250 --> 00:23:43,340 way we were going to go so that was a 531 00:23:47,230 --> 00:23:45,260 major driving force for getting down to 532 00:23:49,900 --> 00:23:47,240 something a bit smaller which is over 533 00:23:52,440 --> 00:23:49,910 here this is still not easy to carry 534 00:23:54,400 --> 00:23:52,450 around it's about 15 kilograms but 535 00:23:58,120 --> 00:23:54,410 certainly a lot better than it used to 536 00:24:01,780 --> 00:23:58,130 be so here's a comparison with what is 537 00:24:03,850 --> 00:24:01,790 available commercially this is a portion 538 00:24:06,010 --> 00:24:03,860 of a rigaku mini flex instrument and 539 00:24:07,870 --> 00:24:06,020 what you don't see in the picture is a 540 00:24:09,910 --> 00:24:07,880 one kilowatt generator and a water 541 00:24:12,190 --> 00:24:09,920 circulator that has to also be set up 542 00:24:16,570 --> 00:24:12,200 with it and this is Ron Peterson the 543 00:24:18,460 --> 00:24:16,580 discoverer of meridiani aight up in 544 00:24:20,290 --> 00:24:18,470 canada in the wintertime so we went up 545 00:24:21,160 --> 00:24:20,300 with him this year and this is what he 546 00:24:24,760 --> 00:24:21,170 took and this is 547 00:24:26,890 --> 00:24:24,770 the incision Tara instrument so the this 548 00:24:28,900 --> 00:24:26,900 instrument is about ten to a hundred 549 00:24:30,820 --> 00:24:28,910 times smaller and all that other 550 00:24:35,050 --> 00:24:30,830 business than than anything else it's 551 00:24:38,050 --> 00:24:35,060 available here's Dave fish this is the 552 00:24:41,050 --> 00:24:38,060 first time when we took chemin for out 553 00:24:43,630 --> 00:24:41,060 to Death Valley to just do some cameo 554 00:24:45,730 --> 00:24:43,640 shots and do some demos we didn't really 555 00:24:48,490 --> 00:24:45,740 take it out there with the idea of doing 556 00:24:50,740 --> 00:24:48,500 science we really took it out there I 557 00:24:52,270 --> 00:24:50,750 wouldn't say as a publicity stunt but 558 00:24:54,160 --> 00:24:52,280 just to show we could do it to show we 559 00:24:57,310 --> 00:24:54,170 could actually take in and swim the 560 00:25:00,940 --> 00:24:57,320 field of gather data Spitsbergen small 561 00:25:04,240 --> 00:25:00,950 barred in 2006 we came out here to 562 00:25:07,360 --> 00:25:04,250 really do science so here's Dave fish on 563 00:25:09,910 --> 00:25:07,370 the top of Sierra fell with our chemin 564 00:25:11,740 --> 00:25:09,920 for instrument its first time anyone 565 00:25:14,200 --> 00:25:11,750 ever did a quantitative analysis in the 566 00:25:16,630 --> 00:25:14,210 field and what we found is there are 567 00:25:18,580 --> 00:25:16,640 some really useful things you can do you 568 00:25:20,710 --> 00:25:18,590 can actually actively generate 569 00:25:22,630 --> 00:25:20,720 hypotheses and test them in the field 570 00:25:25,810 --> 00:25:22,640 along with other people using other 571 00:25:27,460 --> 00:25:25,820 techniques you can identify ephemeral 572 00:25:29,470 --> 00:25:27,470 phases that aren't going to last longer 573 00:25:31,300 --> 00:25:29,480 than a few minutes or a few hours 574 00:25:34,030 --> 00:25:31,310 certainly not long enough to take them 575 00:25:36,940 --> 00:25:34,040 to the lab and you can go through just a 576 00:25:38,680 --> 00:25:36,950 myriad of samples and find samples that 577 00:25:40,540 --> 00:25:38,690 you really want and not have to carry 578 00:25:44,320 --> 00:25:40,550 back the samples that you don't want and 579 00:25:46,000 --> 00:25:44,330 this particularly is interesting for for 580 00:25:48,360 --> 00:25:46,010 example Doug Ming told me when he took 581 00:25:50,410 --> 00:25:48,370 our instrument down to Antarctica 582 00:25:52,330 --> 00:25:50,420 sometimes they don't get their samples 583 00:25:53,980 --> 00:25:52,340 back for a year so it's very good to 584 00:25:55,420 --> 00:25:53,990 make sure you know what you want and 585 00:25:59,290 --> 00:25:55,430 actually get some information on those 586 00:26:02,920 --> 00:25:59,300 samples when you're in the field so 587 00:26:05,800 --> 00:26:02,930 here's next year this is our chemin a 588 00:26:07,510 --> 00:26:05,810 rather are Terra instrument this this 589 00:26:09,730 --> 00:26:07,520 instrument actually philippe Saracen 590 00:26:11,830 --> 00:26:09,740 took this from a napkin drawing to 591 00:26:14,560 --> 00:26:11,840 carrying this on the airplane in six 592 00:26:17,890 --> 00:26:14,570 months and it's a very same instrument I 593 00:26:21,250 --> 00:26:17,900 have today this is on that same mountain 594 00:26:23,230 --> 00:26:21,260 up in Svalbard if you don't know where 595 00:26:25,050 --> 00:26:23,240 it is this is Pittsburgh and its way 596 00:26:28,660 --> 00:26:25,060 north this is the Arctic Circle here 597 00:26:30,250 --> 00:26:28,670 this is way up at about 80 north and the 598 00:26:32,500 --> 00:26:30,260 reason had that gun in the 599 00:26:34,010 --> 00:26:32,510 previous slide is because you really do 600 00:26:36,050 --> 00:26:34,020 have to watch out for polar bears 601 00:26:37,790 --> 00:26:36,060 up there we were actually interrupted by 602 00:26:40,310 --> 00:26:37,800 polar bears a couple of times while we 603 00:26:44,900 --> 00:26:40,320 were doing work here's our first example 604 00:26:46,880 --> 00:26:44,910 of what Spitsbergen anyway of why it's 605 00:26:49,310 --> 00:26:46,890 important to do mineralogy in the field 606 00:26:51,800 --> 00:26:49,320 and I know you can't see the details of 607 00:26:53,480 --> 00:26:51,810 these two patterns but but you can see 608 00:26:56,000 --> 00:26:53,490 right here you can see a couple of Peaks 609 00:26:59,740 --> 00:26:56,010 here and over here you see three peaks 610 00:27:02,420 --> 00:26:59,750 well this is basically a calcite pattern 611 00:27:04,520 --> 00:27:02,430 this was taken aboard ship a few hours 612 00:27:07,490 --> 00:27:04,530 after we collected the sample and this 613 00:27:09,530 --> 00:27:07,500 one on the left was collected at troll 614 00:27:13,010 --> 00:27:09,540 hot springs or I guess you'd call it 615 00:27:16,010 --> 00:27:13,020 warm springs and this line right here 616 00:27:18,320 --> 00:27:16,020 and a few others are indicative of mono 617 00:27:22,190 --> 00:27:18,330 hydrocal site so we were able to find a 618 00:27:24,050 --> 00:27:22,200 an ephemeral phase here that was not 619 00:27:27,980 --> 00:27:24,060 present even when we gotten it in the 620 00:27:29,990 --> 00:27:27,990 boats and got back to the ship second 621 00:27:33,260 --> 00:27:30,000 thing we did up there we had Steve 622 00:27:36,460 --> 00:27:33,270 Squyres along four four four two weeks 623 00:27:38,860 --> 00:27:36,470 of it and we actually ran kind of a mock 624 00:27:42,200 --> 00:27:38,870 mission to Mars kind of a scenario where 625 00:27:45,140 --> 00:27:42,210 Steve Squyres and and the science 626 00:27:47,570 --> 00:27:45,150 operations working group that we defined 627 00:27:49,280 --> 00:27:47,580 state aboard ship and a party when abort 628 00:27:51,590 --> 00:27:49,290 went ashore with the instruments and 629 00:27:54,530 --> 00:27:51,600 what they did is they went to a place 630 00:27:57,830 --> 00:27:54,540 that we'd supposedly never seen took 631 00:28:00,530 --> 00:27:57,840 images the way a rover would took data 632 00:28:04,970 --> 00:28:00,540 the way the instruments would would take 633 00:28:06,350 --> 00:28:04,980 data on MSL and sent that data back to 634 00:28:08,810 --> 00:28:06,360 us and then we were in this little 635 00:28:11,450 --> 00:28:08,820 enclosed room figuring out what to do 636 00:28:13,760 --> 00:28:11,460 next where to go and this shows you some 637 00:28:17,000 --> 00:28:13,770 of the data this is kevin data collected 638 00:28:19,580 --> 00:28:17,010 we decided to go this rock i personally 639 00:28:21,650 --> 00:28:19,590 thought it was a patch of snow so we 640 00:28:25,850 --> 00:28:21,660 called it snowy rock turned out to be 641 00:28:28,130 --> 00:28:25,860 some kind of a granitic nice and when we 642 00:28:29,960 --> 00:28:28,140 went there we analyzed that that's and 643 00:28:33,380 --> 00:28:29,970 so we knew what it was that was pretty 644 00:28:35,090 --> 00:28:33,390 boring stuff Paul Mahaffy decided to 645 00:28:37,240 --> 00:28:35,100 analyze there were actually some lichens 646 00:28:40,820 --> 00:28:37,250 on here so he tried out his Sam 647 00:28:42,920 --> 00:28:40,830 equivalent on the lichens and this 648 00:28:45,400 --> 00:28:42,930 stuff's pretty boring to us so we went 649 00:28:47,680 --> 00:28:45,410 looked at the soil beneath the 650 00:28:49,780 --> 00:28:47,690 smelly rock which shows a lot of 651 00:28:51,910 --> 00:28:49,790 amorphous material and some olivene and 652 00:28:53,560 --> 00:28:51,920 so forth and then we moved on to a 653 00:28:56,380 --> 00:28:53,570 little outcrop that was not too far away 654 00:29:01,030 --> 00:28:56,390 from here and this outcrop actually 655 00:29:03,040 --> 00:29:01,040 contained indications of some hydrosol 656 00:29:06,400 --> 00:29:03,050 alterations so it had some magnesite 657 00:29:08,410 --> 00:29:06,410 presence so we were able to aboard ship 658 00:29:10,360 --> 00:29:08,420 go through the scenario of doing this 659 00:29:12,790 --> 00:29:10,370 with a rover and actually find a place 660 00:29:17,650 --> 00:29:12,800 of interest and go on sample there so 661 00:29:19,870 --> 00:29:17,660 that's that's the story with that that's 662 00:29:21,550 --> 00:29:19,880 out to be a pretty successful campaign 663 00:29:24,040 --> 00:29:21,560 and the next thing we heard Doug Ming 664 00:29:25,900 --> 00:29:24,050 was going to Antarctica so we didn't 665 00:29:29,230 --> 00:29:25,910 want to pass up the opportunity to send 666 00:29:31,390 --> 00:29:29,240 Tara down there so he went I guess with 667 00:29:37,240 --> 00:29:31,400 the Phoenix group down to Antarctica in 668 00:29:39,040 --> 00:29:37,250 January and so here he is actually this 669 00:29:41,370 --> 00:29:39,050 instrument worked in negative 20 degree 670 00:29:43,810 --> 00:29:41,380 weather so it's pretty well ruggedized 671 00:29:46,270 --> 00:29:43,820 he'd really didn't have any standing 672 00:29:47,620 --> 00:29:46,280 orders about what to do so we had to 673 00:29:50,290 --> 00:29:47,630 figure it out for himself but he's 674 00:29:52,390 --> 00:29:50,300 actually a pretty sharp guy so he did a 675 00:29:55,570 --> 00:29:52,400 variety of things one of the things he 676 00:29:57,910 --> 00:29:55,580 did he used mineralogy as an in the 677 00:30:00,520 --> 00:29:57,920 field guide to help out the biologists 678 00:30:01,900 --> 00:30:00,530 there look for nematode populations and 679 00:30:04,420 --> 00:30:01,910 that's not probably the first thing you 680 00:30:06,820 --> 00:30:04,430 think of when you think of quantitative 681 00:30:08,710 --> 00:30:06,830 mineralogy but by tracing the 682 00:30:10,540 --> 00:30:08,720 composition of the soil he was actually 683 00:30:14,920 --> 00:30:10,550 able to point them in the direction of 684 00:30:17,530 --> 00:30:14,930 high nematode populations the second 685 00:30:20,860 --> 00:30:17,540 thing that he did is he was able to map 686 00:30:23,020 --> 00:30:20,870 ancient glacial moraines using using 687 00:30:26,140 --> 00:30:23,030 mineralogy in the way he did this is 688 00:30:29,590 --> 00:30:26,150 that the more recent or more recent 689 00:30:33,040 --> 00:30:29,600 moraines had the sodium sulfate minerals 690 00:30:37,030 --> 00:30:33,050 murabba light and thinner dite and the 691 00:30:39,460 --> 00:30:37,040 more ancient ones had gypsum and calcite 692 00:30:41,260 --> 00:30:39,470 carbonate so by just looking at the 693 00:30:43,930 --> 00:30:41,270 compositions of the phases he could 694 00:30:48,160 --> 00:30:43,940 actually map the edges of these angel a 695 00:30:51,130 --> 00:30:48,170 shelter rains down there Philippe 696 00:30:54,160 --> 00:30:51,140 Saracen took tear up to British Columbia 697 00:30:56,760 --> 00:30:54,170 to the site location for the meridiani 698 00:30:59,620 --> 00:30:56,770 aight discovery and here it is and 699 00:31:02,350 --> 00:30:59,630 basically this is a frozen lake and 700 00:31:03,910 --> 00:31:02,360 these wooden areas like right here these 701 00:31:07,990 --> 00:31:03,920 big log sticking out of here would 702 00:31:10,870 --> 00:31:08,000 actually wick up this this very salty 703 00:31:13,660 --> 00:31:10,880 water and evaporated and the crystals 704 00:31:16,840 --> 00:31:13,670 are found on this wood and and this is 705 00:31:21,670 --> 00:31:16,850 we're ready moretti any height was found 706 00:31:23,500 --> 00:31:21,680 which is a magnesium sulfate 11 with 11 707 00:31:26,950 --> 00:31:23,510 waters it's a very hydrated magnesium 708 00:31:31,000 --> 00:31:26,960 sulfate stable below 2 degrees 709 00:31:33,340 --> 00:31:31,010 centigrade well turns out we didn't find 710 00:31:35,740 --> 00:31:33,350 any more a liteon I'm sorry we didn't 711 00:31:38,080 --> 00:31:35,750 find any riddhi Annie aight it was too 712 00:31:41,980 --> 00:31:38,090 warm that year but this was the 713 00:31:44,050 --> 00:31:41,990 composition of some salts we did find 714 00:31:46,510 --> 00:31:44,060 there and lo and behold when these were 715 00:31:48,970 --> 00:31:46,520 taken back to the lab and analyzed two 716 00:31:52,630 --> 00:31:48,980 weeks later none of this stuff was there 717 00:31:54,610 --> 00:31:52,640 so it's I think it's a big take on 718 00:31:56,650 --> 00:31:54,620 message that the things you collect in 719 00:31:58,480 --> 00:31:56,660 the field may not be the things you 720 00:32:02,890 --> 00:31:58,490 analyze when you bring them back to the 721 00:32:04,920 --> 00:32:02,900 laboratory a month later I went to the 722 00:32:10,450 --> 00:32:04,930 University of Hawaii and I worked with 723 00:32:12,940 --> 00:32:10,460 Jeff Taylor and I'm taking tear over to 724 00:32:15,070 --> 00:32:12,950 the Scarab resolve campaign in November 725 00:32:16,600 --> 00:32:15,080 so I wanted to work with Jeff on just do 726 00:32:19,690 --> 00:32:16,610 a little dry labbing and figure out what 727 00:32:21,100 --> 00:32:19,700 minerals and so forth were present the 728 00:32:23,110 --> 00:32:21,110 first thing Jeff said is well why don't 729 00:32:26,080 --> 00:32:23,120 we try a real lunar sample so he pulled 730 00:32:28,750 --> 00:32:26,090 out a lunar soil sample and we analyzed 731 00:32:31,510 --> 00:32:28,760 it sent it off to one of my co ice Steve 732 00:32:34,060 --> 00:32:31,520 chipra and he sent back a quantitative 733 00:32:37,000 --> 00:32:34,070 analysis and it was just bang on to what 734 00:32:39,640 --> 00:32:37,010 Larry tail Taylor had analyzed by doing 735 00:32:42,640 --> 00:32:39,650 really difficult point counting 736 00:32:45,790 --> 00:32:42,650 techniques ten years earlier so Jeff was 737 00:32:47,560 --> 00:32:45,800 really excited by that so we dropped the 738 00:32:50,080 --> 00:32:47,570 whole project of looking at the Skinner 739 00:32:52,780 --> 00:32:50,090 resolve samples and did nothing but 740 00:32:57,130 --> 00:32:52,790 lunar samples all week so this is a 741 00:33:00,250 --> 00:32:57,140 little graph of a number of samples from 742 00:33:02,800 --> 00:33:00,260 the moon that chemin analyzed versus the 743 00:33:04,540 --> 00:33:02,810 same compositions by point counting you 744 00:33:06,960 --> 00:33:04,550 can see we did a pretty good job with 745 00:33:08,630 --> 00:33:06,970 the exception of a few examples here of 746 00:33:11,300 --> 00:33:08,640 doing the 747 00:33:13,460 --> 00:33:11,310 a same quality of measurement as this 748 00:33:15,050 --> 00:33:13,470 meticulous point counting that literally 749 00:33:17,500 --> 00:33:15,060 took months and months of people's time 750 00:33:20,180 --> 00:33:17,510 on the earth and the chemin instrument 751 00:33:25,220 --> 00:33:20,190 did this in a matter of a couple of 752 00:33:27,230 --> 00:33:25,230 hours for each analysis I came back and 753 00:33:29,960 --> 00:33:27,240 I'd actually talked with we thank jew 754 00:33:31,900 --> 00:33:29,970 whose from the University of Wisconsin I 755 00:33:35,360 --> 00:33:31,910 talked to him at the astrobiology 756 00:33:37,370 --> 00:33:35,370 workshop here rather the the conference 757 00:33:38,780 --> 00:33:37,380 and he asked if he could borrow this 758 00:33:41,510 --> 00:33:38,790 instrument to go on a field trip to 759 00:33:45,530 --> 00:33:41,520 Canada so I said that would be fine so 760 00:33:47,390 --> 00:33:45,540 when I came back I I flew up to Madison 761 00:33:50,300 --> 00:33:47,400 and dropped off the instrument and I 762 00:33:52,910 --> 00:33:50,310 kind of felt like when I left my son off 763 00:33:55,160 --> 00:33:52,920 to his first day of school I got back on 764 00:33:58,430 --> 00:33:55,170 the airplane no instrument no luggage 765 00:34:00,410 --> 00:33:58,440 just got on the plane and left and so we 766 00:34:03,020 --> 00:34:00,420 found we found his students went off 767 00:34:04,460 --> 00:34:03,030 into Canada with this thing and you can 768 00:34:05,960 --> 00:34:04,470 see they went to some very extreme 769 00:34:12,409 --> 00:34:05,970 environments here they were inside a 770 00:34:14,330 --> 00:34:12,419 truckstop bathroom in near sudbury they 771 00:34:20,570 --> 00:34:14,340 needed to recharge the instrument that's 772 00:34:22,550 --> 00:34:20,580 why they went in there anyway so so they 773 00:34:24,590 --> 00:34:22,560 analyzed a whole bunch of samples we've 774 00:34:27,409 --> 00:34:24,600 hang sent me this example of a quarter 775 00:34:29,990 --> 00:34:27,419 green the light thing they got from one 776 00:34:33,110 --> 00:34:30,000 of the banded iron formations and when 777 00:34:36,139 --> 00:34:33,120 they got back to the lab they actually 778 00:34:37,700 --> 00:34:36,149 did some optical microscopy in some tem 779 00:34:41,540 --> 00:34:37,710 and this is actually the Drina light 780 00:34:46,580 --> 00:34:41,550 that was found in the in the xrd from 781 00:34:49,330 --> 00:34:46,590 the field just after that bleep Saracen 782 00:34:52,970 --> 00:34:49,340 took a different terror instrument but 783 00:34:54,800 --> 00:34:52,980 over to Rio Tinto Spain and we've been 784 00:34:58,610 --> 00:34:54,810 over there a couple of times and Rio 785 00:35:00,710 --> 00:34:58,620 Tinto is an ancient mine that has a lot 786 00:35:03,140 --> 00:35:00,720 of iron sulfate sulfides and these are 787 00:35:05,660 --> 00:35:03,150 oxidized to these very interesting iron 788 00:35:08,690 --> 00:35:05,670 sulfate hydrates which we believe are on 789 00:35:12,440 --> 00:35:08,700 Mars some examples of which are on Mars 790 00:35:15,020 --> 00:35:12,450 and a lot of these things are all so 791 00:35:17,510 --> 00:35:15,030 ephemeral so what you what you look at 792 00:35:18,970 --> 00:35:17,520 there may not be in the lab so so we 793 00:35:21,370 --> 00:35:18,980 took a chance and one over there 794 00:35:25,109 --> 00:35:21,380 this is Mark gala numark gallon who's a 795 00:35:28,750 --> 00:35:25,119 French scientist who actually did a 796 00:35:30,670 --> 00:35:28,760 theoretical diagram of the erotica model 797 00:35:32,980 --> 00:35:30,680 of the chemin instrument and actually 798 00:35:35,440 --> 00:35:32,990 came up with a with a ray tracing 799 00:35:37,300 --> 00:35:35,450 simulation so that we change any part of 800 00:35:39,960 --> 00:35:37,310 the instrument and he'll tell us what it 801 00:35:43,270 --> 00:35:39,970 does at the output with with townson and 802 00:35:45,520 --> 00:35:43,280 and range in full with half max of two 803 00:35:47,020 --> 00:35:45,530 theta so I was real happy to see mark in 804 00:35:49,990 --> 00:35:47,030 the field he's just been a just a 805 00:35:51,970 --> 00:35:50,000 mainstay for our program here's an 806 00:35:53,620 --> 00:35:51,980 example of a couple of things we found 807 00:35:56,050 --> 00:35:53,630 out there or Philippe found rather 808 00:35:58,180 --> 00:35:56,060 there's some hydro knee injera site it 809 00:36:02,970 --> 00:35:58,190 was these are just just on the rocks 810 00:36:07,030 --> 00:36:02,980 here from D hydrated salts there's a 811 00:36:11,310 --> 00:36:07,040 example of copia piden coke invite all 812 00:36:14,830 --> 00:36:11,320 so ephemeral mineral on the rocks there 813 00:36:17,770 --> 00:36:14,840 okay so what's next the reason I'm doing 814 00:36:21,220 --> 00:36:17,780 this is I'm interested in offering this 815 00:36:24,190 --> 00:36:21,230 to anyone in the NAI who who cares to do 816 00:36:27,820 --> 00:36:24,200 this kind of a of a field campaign to do 817 00:36:29,650 --> 00:36:27,830 mineralogy and and the cost to anyone 818 00:36:31,180 --> 00:36:29,660 who wants to do it is just the process 819 00:36:33,609 --> 00:36:31,190 of sending it to you and getting it back 820 00:36:37,390 --> 00:36:33,619 as long as you don't drop it from from a 821 00:36:39,820 --> 00:36:37,400 great height and i found the reason i 822 00:36:41,710 --> 00:36:39,830 can i can say this is we found for the 823 00:36:43,900 --> 00:36:41,720 last year that this is a fairly 824 00:36:46,690 --> 00:36:43,910 user-friendly instrument it's very 825 00:36:49,359 --> 00:36:46,700 robust it seems to produce information 826 00:36:52,930 --> 00:36:49,369 that that is valuable from a wide 827 00:36:55,060 --> 00:36:52,940 variety of other disciplines I've 828 00:36:58,330 --> 00:36:55,070 already got it signed up for the rest of 829 00:36:59,770 --> 00:36:58,340 this year to go various places so it's 830 00:37:02,890 --> 00:36:59,780 going just about a different place every 831 00:37:04,390 --> 00:37:02,900 month starting next year though I'll 832 00:37:07,750 --> 00:37:04,400 have two of these things and I'm willing 833 00:37:11,560 --> 00:37:07,760 to work with whoever wants to to take 834 00:37:14,590 --> 00:37:11,570 this in the field so just to conclude 835 00:37:16,000 --> 00:37:14,600 and I hope I have time enough to do a 836 00:37:18,280 --> 00:37:16,010 little demo I actually brought it i'll 837 00:37:22,420 --> 00:37:18,290 show you how you prepare a sample and do 838 00:37:24,520 --> 00:37:22,430 an analysis I think you know Institute 839 00:37:27,520 --> 00:37:24,530 mineralogical analysis is valuable for 840 00:37:29,620 --> 00:37:27,530 astrobiology field campaigns now it's 841 00:37:31,300 --> 00:37:29,630 quite possible for people who aren't 842 00:37:32,860 --> 00:37:31,310 mineralogist to 843 00:37:35,470 --> 00:37:32,870 do mineralogy in the field and i'll show 844 00:37:38,950 --> 00:37:35,480 you how how simple it can be you don't 845 00:37:40,480 --> 00:37:38,960 have to be a mineralogist to do this you 846 00:37:43,600 --> 00:37:40,490 should know a bit something it's more 847 00:37:45,790 --> 00:37:43,610 than a toaster and I think this 848 00:37:47,860 --> 00:37:45,800 real-time in situ mineralogy is a new 849 00:37:49,330 --> 00:37:47,870 concept and I think we don't really know 850 00:37:51,160 --> 00:37:49,340 where it's going to go anytime you do 851 00:37:53,470 --> 00:37:51,170 something new you don't know what all 852 00:37:55,170 --> 00:37:53,480 the applications are going to be I had 853 00:37:59,800 --> 00:37:55,180 no idea we would be able to trace 854 00:38:01,120 --> 00:37:59,810 nematode populations in in Antarctica so 855 00:38:04,330 --> 00:38:01,130 you never know what you're going to find 856 00:38:06,910 --> 00:38:04,340 until you try it so that's it and I 857 00:38:08,980 --> 00:38:06,920 wanted to thank all my various funding 858 00:38:11,530 --> 00:38:08,990 I'd hate to tell you how much money I 859 00:38:13,960 --> 00:38:11,540 spent on this but it was just a ton I'd 860 00:38:16,210 --> 00:38:13,970 like to thank NASA for providing me with 861 00:38:18,400 --> 00:38:16,220 all that money and also to the chemin 862 00:38:21,490 --> 00:38:18,410 team and to institute incorporated which 863 00:38:22,990 --> 00:38:21,500 is philippe Saracens startup company 864 00:38:28,810 --> 00:38:23,000 which has made all this possible so 865 00:38:33,400 --> 00:38:28,820 thanks thank you Dave there is plenty of 866 00:38:35,740 --> 00:38:33,410 time oh so what I suggest is why don't 867 00:38:38,140 --> 00:38:35,750 you go ahead and and get that set up and 868 00:38:40,300 --> 00:38:38,150 if anybody has a question for Dave 869 00:38:42,430 --> 00:38:40,310 during the interim while he's getting 870 00:38:44,530 --> 00:38:42,440 set up this would be a good time to jump 871 00:38:47,260 --> 00:38:44,540 in and you'll have other opportunities 872 00:38:53,520 --> 00:38:47,270 to ask questions as we go along if ever 873 00:39:01,690 --> 00:38:57,070 so here's the instrument about 15 874 00:39:04,590 --> 00:39:01,700 kilograms with batteries and it's got 875 00:39:07,420 --> 00:39:04,600 four hours of life it works off these 876 00:39:11,380 --> 00:39:07,430 laptop batteries and these are 877 00:39:13,120 --> 00:39:11,390 hot-swappable and feel so you can just 878 00:39:15,850 --> 00:39:13,130 take a bunch of batteries and keep 879 00:39:22,210 --> 00:39:15,860 replacing one at a time or you can work 880 00:39:24,790 --> 00:39:22,220 for four hours and and and go home so 881 00:39:29,620 --> 00:39:24,800 let me show you how to to prepare a 882 00:39:32,470 --> 00:39:29,630 sample and load a sample so it's 883 00:39:34,090 --> 00:39:32,480 perfectly safe but you're not going to 884 00:39:36,600 --> 00:39:34,100 be x-rayed by this name or that you'll 885 00:39:39,190 --> 00:39:36,610 be x-rayed by your color television set 886 00:39:42,800 --> 00:39:39,200 the sample goes in there so I'm going to 887 00:39:45,980 --> 00:39:42,810 start start shaking the sample 888 00:39:48,740 --> 00:39:45,990 here okay I'll show you what the sample 889 00:39:52,520 --> 00:39:48,750 consists of it's basically a tuning fork 890 00:39:54,290 --> 00:39:52,530 arrangement and there are two symmetric 891 00:39:57,380 --> 00:39:54,300 sample holders one on each side so you 892 00:39:59,840 --> 00:39:57,390 fill one and not the other and this is 893 00:40:01,730 --> 00:39:59,850 what we call the ashtray so you just you 894 00:40:05,450 --> 00:40:01,740 put it in here at shakes it just as if 895 00:40:06,470 --> 00:40:05,460 it were in the instrument so what I'm 896 00:40:09,710 --> 00:40:06,480 going to do is I'm going to load a 897 00:40:15,920 --> 00:40:09,720 sample and then start it and i'll show 898 00:40:17,660 --> 00:40:15,930 you how to prepare a sample it's not 899 00:40:20,860 --> 00:40:17,670 always as easy assist you don't always 900 00:40:24,140 --> 00:40:20,870 find a bit of your bit of your fireplace 901 00:40:25,610 --> 00:40:24,150 out in the field that so that's what 902 00:40:29,720 --> 00:40:25,620 this is this is a little bit of my 903 00:40:32,690 --> 00:40:29,730 fireplace so this is a 150 micron mesh 904 00:40:33,950 --> 00:40:32,700 screen and all I'm going to do is I'm 905 00:40:48,500 --> 00:40:33,960 going to take this little drumble tool 906 00:40:54,270 --> 00:40:50,849 and I do this in the lab to it's 907 00:40:55,890 --> 00:40:54,280 actually uh it's a very nice way to get 908 00:40:57,930 --> 00:40:55,900 a micro example of something where 909 00:41:01,200 --> 00:40:57,940 you're you're interested in summarizing 910 00:41:02,910 --> 00:41:01,210 enough not other not another horizon so 911 00:41:07,109 --> 00:41:02,920 whatever goes through the screen will 912 00:41:08,370 --> 00:41:07,119 work with Kevin and I don't know if you 913 00:41:10,890 --> 00:41:08,380 can see inside there but there's a 914 00:41:12,390 --> 00:41:10,900 little bit of material in there not too 915 00:41:18,029 --> 00:41:12,400 much but that's certainly not to do the 916 00:41:29,210 --> 00:41:18,039 job so what I'm going to do is I'm going 917 00:41:35,630 --> 00:41:31,790 this material needs to be fairly dry so 918 00:41:37,670 --> 00:41:35,640 that there is an issue with using what 919 00:41:39,550 --> 00:41:37,680 materials they don't really flow into 920 00:41:44,710 --> 00:41:39,560 the cell very well so that's one of the 921 00:41:46,640 --> 00:41:44,720 one of the things we're working on so I 922 00:41:48,560 --> 00:41:46,650 don't know if you can see that but 923 00:41:50,660 --> 00:41:48,570 there's their grains falling in there 924 00:41:54,320 --> 00:41:50,670 and and now they're being shaken around 925 00:41:58,220 --> 00:41:54,330 and filling the filling this this part 926 00:42:01,190 --> 00:41:58,230 right here okay so that's so that 927 00:42:02,720 --> 00:42:01,200 samples ready to go so now what I'm 928 00:42:08,030 --> 00:42:02,730 going to do is I'm just going to drop it 929 00:42:14,480 --> 00:42:08,040 right in here and I'm going to stop 930 00:42:18,109 --> 00:42:14,490 shaking now from here on out this can 931 00:42:21,380 --> 00:42:18,119 either be run by a computer or or by any 932 00:42:23,780 --> 00:42:21,390 kind of web capable device I like to 933 00:42:28,400 --> 00:42:23,790 know I have time I'll show you I can run 934 00:42:29,900 --> 00:42:28,410 it up my Mac iPhone so this is going to 935 00:42:33,650 --> 00:42:29,910 be tough doing this left-handed 936 00:42:35,780 --> 00:42:33,660 backwards let's see okay so this is the 937 00:42:37,670 --> 00:42:35,790 basic there only four commands on the 938 00:42:40,280 --> 00:42:37,680 instrument so it's just that easy to use 939 00:42:42,740 --> 00:42:40,290 it you can't make it has to be that way 940 00:42:44,750 --> 00:42:42,750 or I would have messed it up so this is 941 00:42:47,780 --> 00:42:44,760 the where you run everything from the 942 00:42:52,870 --> 00:42:47,790 status menu dis click this arrow say go 943 00:42:59,640 --> 00:42:52,880 and and you have to give it a name and 944 00:43:09,060 --> 00:43:04,880 I'll say Blake's fireplace okay and 945 00:43:11,700 --> 00:43:09,070 start so here and start going here 946 00:43:15,090 --> 00:43:11,710 pretty soon ok so it's vibrating the 947 00:43:18,810 --> 00:43:15,100 sample and the x-ray beams on is taking 948 00:43:20,670 --> 00:43:18,820 an analysis and the status menu here 949 00:43:21,930 --> 00:43:20,680 tells you exactly what it's doing this 950 00:43:23,670 --> 00:43:21,940 isn't this wouldn't be where you'd want 951 00:43:26,790 --> 00:43:23,680 to look all the time but just to make 952 00:43:30,300 --> 00:43:26,800 sure things are doing okay to look at 953 00:43:35,520 --> 00:43:30,310 the data you go to the data point here 954 00:43:37,470 --> 00:43:35,530 the little data flag and since this is 955 00:43:39,480 --> 00:43:37,480 this is actually talking to a computer 956 00:43:41,220 --> 00:43:39,490 that's running a web interface so you're 957 00:43:44,150 --> 00:43:41,230 actually talking through the computer to 958 00:43:46,380 --> 00:43:44,160 another computer that's running the web 959 00:43:48,480 --> 00:43:46,390 okay there's there's the first pattern 960 00:43:49,680 --> 00:43:48,490 and not I have no idea if you can all 961 00:43:58,410 --> 00:43:49,690 right you know what I can I can hook 962 00:44:03,210 --> 00:43:58,420 that up here I can now turn this to in 963 00:44:20,730 --> 00:44:03,220 my direction Oh which oh ok well I'll 964 00:44:36,039 --> 00:44:23,340 so I close this and open it to make it 965 00:44:41,410 --> 00:44:38,819 okay so basically a pattern is 966 00:44:45,130 --> 00:44:41,420 developing what what this thing does is 967 00:44:47,650 --> 00:44:45,140 every 10 seconds it exposes the CCD well 968 00:44:51,669 --> 00:44:47,660 there we go okay now I get to use my 969 00:44:54,189 --> 00:44:51,679 real laser pointer so basically every 970 00:44:57,130 --> 00:44:54,199 now it's done six exposure so far every 971 00:44:58,799 --> 00:44:57,140 10 seconds it collects another analysis 972 00:45:03,390 --> 00:44:58,809 and sums it into the one you're seeing 973 00:45:06,419 --> 00:45:03,400 now that this does do x-ray fluorescence 974 00:45:15,309 --> 00:45:06,429 and if you want to do x-ray fluorescence 975 00:45:16,870 --> 00:45:15,319 you go to X or up so this shows you the 976 00:45:19,059 --> 00:45:16,880 x-ray fluorescence pattern that's been 977 00:45:22,660 --> 00:45:19,069 generated and what you see is there's 978 00:45:25,719 --> 00:45:22,670 the cobalt of K alpha K beta from the 979 00:45:26,559 --> 00:45:25,729 two there is a little bit of iron in 980 00:45:31,179 --> 00:45:26,569 here I don't know where they aren't 981 00:45:34,120 --> 00:45:31,189 coming from there's calcium maybe I 982 00:45:40,329 --> 00:45:37,120 oh this is going in but you can see the 983 00:45:42,490 --> 00:45:40,339 calcium peak so it gives you an idea you 984 00:45:45,759 --> 00:45:42,500 might be seeing my fireplace is just 985 00:45:49,120 --> 00:45:45,769 made out of calcite can't go back to 986 00:45:50,589 --> 00:45:49,130 x-ray diffraction mode now 11 feature 987 00:45:53,079 --> 00:45:50,599 this is you don't even need to have a 988 00:45:55,960 --> 00:45:53,089 computer to go in the field this thing 989 00:45:59,440 --> 00:45:55,970 will collect everything just from the 990 00:46:01,420 --> 00:45:59,450 front panel and here's a here's 991 00:46:03,999 --> 00:46:01,430 everything that this is every selected 992 00:46:06,579 --> 00:46:04,009 it has a big hard drive on here and so 993 00:46:09,099 --> 00:46:06,589 every pattern has ever been affected by 994 00:46:10,900 --> 00:46:09,109 this instrument is stored every single 995 00:46:13,630 --> 00:46:10,910 image from every pattern so everything 996 00:46:16,539 --> 00:46:13,640 can be re calculated later on if you 997 00:46:23,579 --> 00:46:16,549 ponder some mistake I can go down here 998 00:46:30,209 --> 00:46:26,969 there's the opal CT that I showed you in 999 00:46:34,349 --> 00:46:30,219 my it's the opal CT pattern that i 1000 00:46:36,089 --> 00:46:34,359 showed you that was taken March 22nd so 1001 00:46:37,469 --> 00:46:36,099 all the data is resident in the 1002 00:46:39,150 --> 00:46:37,479 instrument so you don't really have to 1003 00:46:42,589 --> 00:46:39,160 take computer in the field but if you 1004 00:46:46,589 --> 00:46:42,599 want to do analyses in the field you do 1005 00:46:54,000 --> 00:46:46,599 now I can also run this from my from my 1006 00:46:54,010 --> 00:47:02,099 and so if I go to data 1007 00:47:02,109 --> 00:47:08,390 okay so i'm going to change this to xrl 1008 00:47:12,120 --> 00:47:10,470 well this is kind of a part of it I 1009 00:47:16,799 --> 00:47:12,130 really want to show you the real deal 1010 00:47:19,890 --> 00:47:16,809 okay so here's it so here's the xrd 1011 00:47:22,140 --> 00:47:19,900 pattern now this is a perfectly a 1012 00:47:25,890 --> 00:47:22,150 pattern analyzed right now so let's why 1013 00:47:29,400 --> 00:47:25,900 don't we do that mean so yes this is a 1014 00:47:32,460 --> 00:47:29,410 weak point with consoling a we we cannot 1015 00:47:36,509 --> 00:47:32,470 see you we try all kinds of a method and 1016 00:47:38,970 --> 00:47:36,519 no child too okay actually need a 1017 00:47:41,640 --> 00:47:38,980 question for you Dave okay I'm tones are 1018 00:47:45,269 --> 00:47:41,650 going to take the mark the Mars machine 1019 00:47:50,269 --> 00:47:45,279 to do this to load a sample and I'm not 1020 00:47:54,269 --> 00:47:50,279 it good question a lot slower than this 1021 00:47:57,029 --> 00:47:54,279 basically the 11 MSL gets to an outcrop 1022 00:47:59,130 --> 00:47:57,039 it's probably going to be six days to a 1023 00:48:02,549 --> 00:47:59,140 week to do a full workup if everything 1024 00:48:05,130 --> 00:48:02,559 works fine and for it will go through 1025 00:48:07,979 --> 00:48:05,140 all the remote sensing the contact 1026 00:48:09,660 --> 00:48:07,989 instrument stuff there will be you know 1027 00:48:12,809 --> 00:48:09,670 ground in the loop to figure out what to 1028 00:48:15,450 --> 00:48:12,819 do next will decide to collect a sample 1029 00:48:18,720 --> 00:48:15,460 or not that sample is collected by the 1030 00:48:20,099 --> 00:48:18,730 drill the news the new drill is actually 1031 00:48:23,460 --> 00:48:20,109 a percussion drill there's no pressure 1032 00:48:26,249 --> 00:48:23,470 on MSL now so it thrills and crushes a 1033 00:48:31,079 --> 00:48:26,259 sample it's sieve and then that sample 1034 00:48:32,819 --> 00:48:31,089 is delivered to Kevin and Sam and that 1035 00:48:35,099 --> 00:48:32,829 whole process will probably take four or 1036 00:48:38,220 --> 00:48:35,109 five or maybe six days and on the last 1037 00:48:41,309 --> 00:48:38,230 day or two then Sam where Kevin will do 1038 00:48:42,970 --> 00:48:41,319 an analysis we analyzed at night because 1039 00:48:46,300 --> 00:48:42,980 it's colder and that's what we 1040 00:48:49,120 --> 00:48:46,310 like to have we expect that we may take 1041 00:48:51,730 --> 00:48:49,130 as long as 10 hours to do a single 1042 00:48:54,550 --> 00:48:51,740 analysis depending on how complex the 1043 00:48:55,870 --> 00:48:54,560 material is for obvious reasons we 1044 00:48:58,000 --> 00:48:55,880 wanted to make this thing a lot faster 1045 00:48:59,950 --> 00:48:58,010 than MSL because you don't want to sit 1046 00:49:02,530 --> 00:48:59,960 there for two days waiting for the 1047 00:49:05,980 --> 00:49:02,540 result so this is about I would say 20 1048 00:49:09,700 --> 00:49:05,990 time 25 times faster to that enough msl 1049 00:49:12,580 --> 00:49:09,710 is so yeah I'll take a probably to two 1050 00:49:15,040 --> 00:49:12,590 nights of data and and that'll give us 1051 00:49:18,910 --> 00:49:15,050 what we're seeing here you go in about 1052 00:49:21,670 --> 00:49:18,920 two or three hours with dave is there 1053 00:49:24,040 --> 00:49:21,680 anything that we've learned about the 1054 00:49:28,840 --> 00:49:24,050 properties of the soil from mars phoenix 1055 00:49:31,240 --> 00:49:28,850 that leads you to consider any changes 1056 00:49:33,820 --> 00:49:31,250 or any aspects of the way you're 1057 00:49:37,359 --> 00:49:33,830 requiring a sample and getting it in the 1058 00:49:39,490 --> 00:49:37,369 instrument on MSL um a lot of that stuff 1059 00:49:41,710 --> 00:49:39,500 yeah good yeah that's that's a great 1060 00:49:44,710 --> 00:49:41,720 question we're really thinking a lot 1061 00:49:46,750 --> 00:49:44,720 about that now well Doug man who's on my 1062 00:49:49,359 --> 00:49:46,760 team it's also one of the Phoenix guys 1063 00:49:51,010 --> 00:49:49,369 so and he's a soil scientist so we're 1064 00:49:54,730 --> 00:49:51,020 we're puzzling over some of those 1065 00:49:58,510 --> 00:49:54,740 results my first answer is let Sam try 1066 00:50:02,260 --> 00:49:58,520 it first then we'll do it and the thing 1067 00:50:04,240 --> 00:50:02,270 that I'm mostly worried about is some of 1068 00:50:06,220 --> 00:50:04,250 my other co eyes day vanaman Dave fish 1069 00:50:08,170 --> 00:50:06,230 and Steve chipra have done a lot of work 1070 00:50:11,380 --> 00:50:08,180 on iron sulfate hydrates and these 1071 00:50:13,480 --> 00:50:11,390 things are real nasty things some of 1072 00:50:15,130 --> 00:50:13,490 these things can can when you warm them 1073 00:50:17,950 --> 00:50:15,140 up they'll go through a liquid phase 1074 00:50:20,410 --> 00:50:17,960 make a slurry and then lose water and 1075 00:50:21,820 --> 00:50:20,420 turn into cement so we certainly don't 1076 00:50:26,599 --> 00:50:21,830 want that in our funnel when we're 1077 00:50:31,700 --> 00:50:28,729 what I would like to do is have a wait 1078 00:50:34,700 --> 00:50:31,710 and see thing to just watch the property 1079 00:50:37,099 --> 00:50:34,710 stuff before we do anything I know you 1080 00:50:39,680 --> 00:50:37,109 know Sam wants to and so do i want to 1081 00:50:41,660 --> 00:50:39,690 see exactly what's there but I want to 1082 00:50:43,970 --> 00:50:41,670 be a little cautious in the beginning to 1083 00:50:45,559 --> 00:50:43,980 make sure we don't force them cemented 1084 00:50:52,729 --> 00:50:45,569 in our funnel one that will be the end 1085 00:50:54,410 --> 00:50:52,739 of it okay any more questions or okay 1086 00:50:56,870 --> 00:50:54,420 i'll show you how we how we analyze this 1087 00:50:58,970 --> 00:50:56,880 there's so you see there's a there's a 1088 00:51:01,509 --> 00:50:58,980 very nice pretty nice diffraction 1089 00:51:06,349 --> 00:51:01,519 pattern developing so i'm going to go to 1090 00:51:08,380 --> 00:51:06,359 files and i'm going to download one of 1091 00:51:11,960 --> 00:51:08,390 these patterns so i'm going to download 1092 00:51:13,489 --> 00:51:11,970 the k alpha pattern right here and what 1093 00:51:15,589 --> 00:51:13,499 I'm doing right now is I'm taking it off 1094 00:51:17,269 --> 00:51:15,599 the computer on the instrument and 1095 00:51:22,940 --> 00:51:17,279 bringing it on to the computer that's 1096 00:51:25,039 --> 00:51:22,950 onto this computer okay and I brought 1097 00:51:26,839 --> 00:51:25,049 down a format which is compatible with a 1098 00:51:30,079 --> 00:51:26,849 commercial program which I have on this 1099 00:51:33,200 --> 00:51:30,089 machine so so here we go we're opening 1100 00:51:36,620 --> 00:51:33,210 up this materials data J program there's 1101 00:51:39,920 --> 00:51:36,630 the very same pattern in Jade i also 1102 00:51:41,390 --> 00:51:39,930 have and i'll have the j program which 1103 00:51:43,880 --> 00:51:41,400 is a search match and quantitative 1104 00:51:46,489 --> 00:51:43,890 analysis program but also I have the I 1105 00:51:48,259 --> 00:51:46,499 CBD powder file which is which is the 1106 00:51:49,870 --> 00:51:48,269 powder complete powder file of all the 1107 00:51:52,609 --> 00:51:49,880 minerals that are that are known 1108 00:51:56,720 --> 00:51:52,619 resident on the machine so the first 1109 00:51:59,059 --> 00:51:56,730 thing I would do is go to search match 1110 00:52:01,819 --> 00:51:59,069 and say I want to look in the minerals 1111 00:52:08,630 --> 00:52:01,829 files to see what this is until it to go 1112 00:52:09,710 --> 00:52:08,640 and it asked me a few questions and well 1113 00:52:14,960 --> 00:52:09,720 there you go looks like Blake's 1114 00:52:18,499 --> 00:52:14,970 fireplace it's calcite so that was kind 1115 00:52:21,229 --> 00:52:18,509 of a trivial example but it'll do the 1116 00:52:22,940 --> 00:52:21,239 same with complex things I wanted to 1117 00:52:29,479 --> 00:52:22,950 give myself something easy so I didn't 1118 00:52:32,720 --> 00:52:29,489 screw it up question yes this is John it 1119 00:52:35,509 --> 00:52:32,730 aims it's a great instrument have you 1120 00:52:37,700 --> 00:52:35,519 thought about missions beyond MSL for 1121 00:52:39,440 --> 00:52:37,710 example sending it on some small 1122 00:52:42,440 --> 00:52:39,450 spacecraft to go and check out some of 1123 00:52:46,460 --> 00:52:42,450 the near-earth asteroids absolutely 1124 00:52:48,019 --> 00:52:46,470 we're actually working on yeah that one 1125 00:52:52,819 --> 00:52:48,029 thing we have to do is make it smaller 1126 00:52:55,609 --> 00:52:52,829 and we actually are building a shoebox 1127 00:52:57,049 --> 00:52:55,619 sized instrument now and which we're 1128 00:53:00,759 --> 00:52:57,059 going to take down the scare of resolve 1129 00:53:03,019 --> 00:53:00,769 campaign and it literally is it's about 1130 00:53:05,120 --> 00:53:03,029 it's half the size of this so we're 1131 00:53:08,150 --> 00:53:05,130 getting down to something we think can 1132 00:53:11,210 --> 00:53:08,160 be run on smaller missions we're 1133 00:53:13,940 --> 00:53:11,220 shooting for five kilograms about 1134 00:53:16,400 --> 00:53:13,950 shoebox-sized and that includes an 1135 00:53:18,559 --> 00:53:16,410 automatic sample delivery system so the 1136 00:53:21,589 --> 00:53:18,569 you poor crushed material in there it'll 1137 00:53:23,809 --> 00:53:21,599 it'll sort it into the left plus 150 1138 00:53:26,059 --> 00:53:23,819 micron material and deliver that to the 1139 00:53:28,460 --> 00:53:26,069 sample holder so we're we have that 1140 00:53:30,940 --> 00:53:28,470 design we're building it and actually 1141 00:53:34,249 --> 00:53:30,950 have a couple proposals in right now to 1142 00:53:36,859 --> 00:53:34,259 do something like that but yeah I'm 1143 00:53:38,809 --> 00:53:36,869 hopeful we can go to this is just a 1144 00:53:42,410 --> 00:53:38,819 general purpose instrumented it's been 1145 00:53:44,420 --> 00:53:42,420 proposed for a variety places already my 1146 00:53:46,279 --> 00:53:44,430 first proposal was pretty much paper 1147 00:53:48,220 --> 00:53:46,289 where that was funny they did the old 1148 00:53:50,500 --> 00:53:48,230 sham wholly-owned for the 1149 00:53:53,590 --> 00:53:50,510 was that a mission I proposed this in 1150 00:53:54,880 --> 00:53:53,600 1992 with barely more than a napkin 1151 00:53:57,040 --> 00:53:54,890 drawing they were lucky they didn't 1152 00:54:05,680 --> 00:53:57,050 choose me but yeah I've been trying 1153 00:54:08,080 --> 00:54:05,690 variety things I heard it which is a 1154 00:54:10,510 --> 00:54:08,090 walk-in able to really my need to 1155 00:54:13,710 --> 00:54:10,520 exercise on my family man instantly 1156 00:54:19,510 --> 00:54:13,720 something that's under tension is 1157 00:54:22,150 --> 00:54:19,520 building her basically that the 1158 00:54:24,810 --> 00:54:22,160 beginning of it was a dang I wish I had 1159 00:54:29,320 --> 00:54:24,820 brought this you know I figured this out 1160 00:54:31,359 --> 00:54:29,330 when I was a postdoc and I used to go 1161 00:54:33,400 --> 00:54:31,369 use his carbon code or over in another 1162 00:54:36,240 --> 00:54:33,410 building and there were all these gave I 1163 00:54:39,460 --> 00:54:36,250 think repeating the question I I see 1164 00:54:42,310 --> 00:54:39,470 somebody but rachel is what concert it 1165 00:54:44,260 --> 00:54:42,320 was what kinds of technologies were were 1166 00:54:48,460 --> 00:54:44,270 useful or were necessary to make this 1167 00:54:50,710 --> 00:54:48,470 small okay yeah I came up with this idea 1168 00:54:52,270 --> 00:54:50,720 when I was a postdoc at Ames and I and I 1169 00:54:54,880 --> 00:54:52,280 was running rummaging through a bunch of 1170 00:54:57,520 --> 00:54:54,890 drawers of stuff and I found this little 1171 00:55:00,970 --> 00:54:57,530 x-ray camera from the 40s to film 1172 00:55:03,580 --> 00:55:00,980 cameras called a micro focus camera and 1173 00:55:06,520 --> 00:55:03,590 it's about the size of a large orange 1174 00:55:08,230 --> 00:55:06,530 and so that was my goal to make 1175 00:55:12,580 --> 00:55:08,240 something electronic that would be that 1176 00:55:14,770 --> 00:55:12,590 side so the first component we worked on 1177 00:55:16,990 --> 00:55:14,780 was the camera and the camera we got 1178 00:55:20,500 --> 00:55:17,000 down to about this size not in cap not 1179 00:55:24,400 --> 00:55:20,510 counted electronics the real issue was 1180 00:55:28,120 --> 00:55:24,410 the x-ray tube and power supplies are 1181 00:55:30,609 --> 00:55:28,130 just a tough business and so we now have 1182 00:55:32,440 --> 00:55:30,619 power supplies that we didn't we didn't 1183 00:55:35,020 --> 00:55:32,450 make that they were made by a commercial 1184 00:55:38,140 --> 00:55:35,030 like oxford instruments that are all 1185 00:55:40,300 --> 00:55:38,150 about this size way about half a 1186 00:55:42,849 --> 00:55:40,310 kilogram so we're getting much better in 1187 00:55:44,530 --> 00:55:42,859 that regard and i would say mostly you 1188 00:55:47,200 --> 00:55:44,540 know once we get the geometry which is a 1189 00:55:49,990 --> 00:55:47,210 which is the compact geometry we needed 1190 00:55:52,290 --> 00:55:50,000 to make the cameras small and then make 1191 00:55:54,670 --> 00:55:52,300 the x-ray too small a power supply so 1192 00:55:58,150 --> 00:55:54,680 we're obviously getting going in the 1193 00:55:59,859 --> 00:55:58,160 right direction i'm hoping to get it 1194 00:56:01,810 --> 00:55:59,869 smaller than five kilograms i don't know 1195 00:56:04,750 --> 00:56:01,820 if we're going to get there certainly a 1196 00:56:12,190 --> 00:56:04,760 little bit but not not one not two but 1197 00:56:19,559 --> 00:56:12,200 maybe three are there any other 1198 00:56:28,079 --> 00:56:21,660 well if not let's thank our speaker 1199 00:56:31,819 --> 00:56:28,089 again reminder of index director seven 1200 00:56:35,069 --> 00:56:31,829 RPG at the end of September will be on 1201 00:56:36,959 --> 00:56:35,079 September 29th and it will be norm sleep 1202 00:56:39,870 --> 00:56:36,969 telling us about the habitability of 1203 00:56:41,670 --> 00:56:39,880 super Earths so thanks everybody and